کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7214430 | 1469464 | 2018 | 23 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Functionalized MWCNTs modified flame retardant PLA nanocomposites and cold rolling process for improving mechanical properties
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
سایر رشته های مهندسی
مهندسی (عمومی)
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
10-hydroxy-9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO-OH) has been successfully covalently grafted onto the surfaces of multi-walled carbon nanotubes (MWCNTs) to obtain DOPO-functionalized MWCNTs (MWCNT-DOPO-OH) by a three-step process. The resultant core-shell nanostructured MWCNT-DOPO-OH was introduced into aluminum hypophosphite/poly(lactic acid) (AHP/PLA) flame retardant systems via melt blending to improve both flame retardancy and mechanical properties. AHP/PLA/MWCNT-DOPO-OH nanocomposites with synergistic effect of 1â¯wt.% MWCNT-DOPO-OH and 14â¯wt.% AHP were shown to be effective in improving flame retardancy with UL 94 V-0 rating and limiting oxygen index (LOI) value of 28.6. And these flame-retardant nanocomposites show a usable Tg higher than 57.8â¯Â°C and much higher char yield for preventing the anti-dropping. Moreover, a cold rolling process was performed for AHP/PLA/MWCNT-DOPO-OH nanocomposites to further improve the mechanical properties for secondary processing. For 1â¯wt.% MWCNT-DOPO-OH loading PLA nanocomposites, the tensile strength increased from 69.5â¯MPa to 77.9â¯MPa and 82.0â¯MPa, and the fracture strain increased from 17.9% to 27.5% and 120%, at rolling ratios of 30% and 50%, respectively, indicating that MWCNT-DOPO-OH modified PLA was homogenized plastic deformation during the rolling process.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Composites Science and Technology - Volume 161, 16 June 2018, Pages 39-49
Journal: Composites Science and Technology - Volume 161, 16 June 2018, Pages 39-49
نویسندگان
Liqiang Gu, Jianhui Qiu, Youwei Yao, Eiichi Sakai, Liting Yang,