کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7214430 1469464 2018 23 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Functionalized MWCNTs modified flame retardant PLA nanocomposites and cold rolling process for improving mechanical properties
موضوعات مرتبط
مهندسی و علوم پایه سایر رشته های مهندسی مهندسی (عمومی)
پیش نمایش صفحه اول مقاله
Functionalized MWCNTs modified flame retardant PLA nanocomposites and cold rolling process for improving mechanical properties
چکیده انگلیسی
10-hydroxy-9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO-OH) has been successfully covalently grafted onto the surfaces of multi-walled carbon nanotubes (MWCNTs) to obtain DOPO-functionalized MWCNTs (MWCNT-DOPO-OH) by a three-step process. The resultant core-shell nanostructured MWCNT-DOPO-OH was introduced into aluminum hypophosphite/poly(lactic acid) (AHP/PLA) flame retardant systems via melt blending to improve both flame retardancy and mechanical properties. AHP/PLA/MWCNT-DOPO-OH nanocomposites with synergistic effect of 1 wt.% MWCNT-DOPO-OH and 14 wt.% AHP were shown to be effective in improving flame retardancy with UL 94 V-0 rating and limiting oxygen index (LOI) value of 28.6. And these flame-retardant nanocomposites show a usable Tg higher than 57.8 °C and much higher char yield for preventing the anti-dropping. Moreover, a cold rolling process was performed for AHP/PLA/MWCNT-DOPO-OH nanocomposites to further improve the mechanical properties for secondary processing. For 1 wt.% MWCNT-DOPO-OH loading PLA nanocomposites, the tensile strength increased from 69.5 MPa to 77.9 MPa and 82.0 MPa, and the fracture strain increased from 17.9% to 27.5% and 120%, at rolling ratios of 30% and 50%, respectively, indicating that MWCNT-DOPO-OH modified PLA was homogenized plastic deformation during the rolling process.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Composites Science and Technology - Volume 161, 16 June 2018, Pages 39-49
نویسندگان
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