کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7214887 | 1469470 | 2018 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Crystallization and morphological and crystal structures of PP in an in situ microfibrillar composite of modified PA66 with PP
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
سایر رشته های مهندسی
مهندسی (عمومی)
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
An in situ-profiled microfibril-reinforced composite of modified polyamide 66 (mPA66) with polypropylene (PP) was prepared using a non-conventional compatibilization technique. The scanning electron microscope morphological observations showed in situ-generated, profiled microfibrils with a non-uniform diameter distribution and very rough surfaces with many pits and knots. The pits and knots were confirmed by the compatibilizer diffusion determined by the energy dispersive spectrum analysis. The presence of the PA66-profiled microfibrils shows the significant nucleation ability of the PP crystallization. Differential scanning calorimetry observations illustrated that the profiled microfibrils can accelerate the crystallization rate and increase the crystallization temperature. Obvious transcrystallization layers were observed through a polarized optical microscope. The β-crystalline phase of PP and larger, long period lamellar stacks were identified by small and wide-angle X-ray scattering measurements, respectively. These observations were very different from those of the simply blended samples of PP/PA66 in the presence or absence of the compatibilizer. Thus, the profiled microfibrils and improved interface adhesion may account for the powerful influence of PP on the crystallization and crystal structure.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Composites Science and Technology - Volume 155, 8 February 2018, Pages 205-212
Journal: Composites Science and Technology - Volume 155, 8 February 2018, Pages 205-212
نویسندگان
Linghe Cheng, Jingwu Wang,