کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7378189 | 1480123 | 2016 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A model for diffusive systems: Beyond the Arrhenius mechanism
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موضوعات مرتبط
مهندسی و علوم پایه
ریاضیات
فیزیک ریاضی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Diffusivity in supercooled liquids was observed to exhibit a non-Arrhenius behavior near the glass-transition temperature. This process, which occurs where the activation energy depends on the temperature, suggests the possibility of a metastable equilibrium. This peculiar phenomenon cannot be explained using the usual Markovian stochastic models. Based on a non-linear Fokker-Planck equation, we propose a diffusion coefficient that is proportional to the supercooled-liquid concentration. The proposed model allows us to explain the anomalous behavior of the diffusivity robustly. We demonstrate that this new approach is consistent with experimental patterns. Besides, it could be applied to non-Arrhenius chemical kinetics.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Physica A: Statistical Mechanics and its Applications - Volume 450, 15 May 2016, Pages 317-322
Journal: Physica A: Statistical Mechanics and its Applications - Volume 450, 15 May 2016, Pages 317-322
نویسندگان
A.C.P. Jr., Pablo Vaveliuk, Kleber C. Mundim, M.A. Moret,