کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7589357 | 1492091 | 2016 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Microfabricated interdigitated Au electrode for voltammetric determination of lead and cadmium in Chinese mitten crab (Eriocheir sinensis)
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
An in-situ plating bismuth modified interdigitated Au electrode (IAE) was developed for determination of Pb2+ and Cd2+ in crab. The IAE was fabricated and used as counter electrode and working electrode. Cyclic voltammetry (CV) was performed with the IAE for studying electrochemical performance, showing clear redox peaks. The key operational parameters were optimized, which were 600 μg Lâ1 of Bi3+ concentration, 0.1 mol Lâ1 of acetate buffer (pH 4.5), â1.2 V of deposition potential and 180 s of deposition time. Under optimized condition, the linear range of IAE was from 5 to 50 μg Lâ1 for both metal ions, with detection limit (threefold signal-to-noise) of 0.74 μg Lâ1 for Pb2+ and 0.86 μg Lâ1 for Cd2+. Finally, the developed sensor was applied to detect Pb2+ and Cd2+ in crab extract solutions by standard addition method. The results were in good agreement with outcomes obtained by inductively coupled plasma mass spectrometry.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Food Chemistry - Volume 201, 15 June 2016, Pages 190-196
Journal: Food Chemistry - Volume 201, 15 June 2016, Pages 190-196
نویسندگان
Xu Yiwei, Zhang Wen, Shi Jiyong, Zou Xiaobo, Li Zhihua, Zhu Yaodi,