کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7600583 | 1492143 | 2014 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Development of a simple extraction and oxidation procedure for the residue analysis of imidacloprid and its metabolites in lettuce using gas chromatography
ترجمه فارسی عنوان
توسعه یک روش استخراج ساده و روش اکسیداسیون برای تجزیه و تحلیل باقی مانده از ایمیداکلوپرید و متابولیت های آن در کاهو با استفاده از کروماتوگرافی گاز
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
چکیده انگلیسی
Simple extraction and optimised oxidation procedures were developed for the determination of the total residues of imidacloprid and its metabolites (containing the 6-chloropicolyl moiety) in lettuce using a gas chromatography-micro electron capture detector (GC-μECD). Samples were extracted with acetonitrile, and the extract was then evaporated. The remaining residues were dissolved in water and oxidised with potassium permanganate to yield 6-chloronicotinic acid (6-CAN). The acid residues were further dissolved in n-hexane:acetone (8:2, v/v) and then silylated with MSTFA (N-methyl-N-(trimethylsilyl)trifluoroacetamide) to 6-chloronicotinic acid trimethylsilyl ester. Calibration curves were linear over the concentration ranges (0.025-5 μg mLâ1) with a determination coefficient (r2) of 0.991. The limits of detection and quantification were 0.015 and 0.05 mg kgâ1, respectively. Recoveries at two fortification levels ranged between 72.8% and 108.3% with relative standard deviation (RSD) lower than 8%. The method was effective, and sensitive enough to determine the total residues of imidacloprid and its metabolites in field-incurred lettuce samples. The identity of the analyte was confirmed using gas chromatography-tandem mass spectrometry (GC-MS/MS).
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Food Chemistry - Volume 148, 1 April 2014, Pages 402-409
Journal: Food Chemistry - Volume 148, 1 April 2014, Pages 402-409
نویسندگان
Ah-Young Ko, Md. Musfiqur Rahman, A.M. Abd El-Aty, Jin Jang, Jong-Hyouk Park, Soon-Kil Cho, Jae-Han Shim,