Reactions of V4O10+ cluster ions with simple inorganic and organic molecules

- Reactions of V4O10+ ions with H2, CO, CH4, C2H2, C2H4, and C2H6 were studied by QH-TOF-MS.
- The homolytic HH splitting rather than the water formation was identified.
- Double oxygen atom transfer reaction with C2H2 was identified.
- The increased velocity of the cluster ions favors the oxygen atom transfer reaction with C2H6.