Temperature dependent ultrasonic properties of aluminium nitride

Hexagonal wurtzite structured aluminium nitride has been characterized by the theoretical calculation of ultrasonic attenuation, ultrasonic velocity, higher order elastic constants, thermal relaxation time, acoustic coupling constants and other related parameters in temperature range 200–800 K for wave propagation along the unique axis of the crystal. Higher order elastic constants of AlN at different temperatures are calculated using Lennard-Jones potential for the determination of ultrasonic attenuation. A decrease in ultrasonic velocity with temperature has been predicted, which is caused by reduction in higher order elastic constants with temperature. The temperature dependent ultrasonic properties have been discussed in correlation with higher order elastic constants, thermal relaxation time, thermal conductivity, acoustic coupling constants and thermal energy density. Anomalous behaviour of the attenuation is found at 400 K. On the basis of attenuation, the ductility and performance of AlN have been studied.