کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
762269 | 1462910 | 2006 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Decomposition of a long chain saturated fatty acid with some additives in hot compressed water
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی انرژی
انرژی (عمومی)
پیش نمایش صفحه اول مقاله
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چکیده انگلیسی
Stearic acid (C17H35COOH: C17-acid) was treated using a batch reactor with supercritical water (SCW) of 673 K and 0.17 g/cm3 for 30 min. In SCW, C17-acid was stable (2% conversion) and the main products were CO2 and C16 alkene. An addition of alkali hydroxide (NaOH and KOH) in the SCW reaction enhanced the decarboxylation of C17-acid with the main products being CO2 and C17 alkane. Metal oxides (CeO2, Y2O3 and ZrO2) enhanced the decarboxylation of C17-acid and the main products were CO2 and C16 alkene. Based on the results, the reaction mechanism was proposed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Energy Conversion and Management - Volume 47, Issues 18–19, November 2006, Pages 3344–3350
Journal: Energy Conversion and Management - Volume 47, Issues 18–19, November 2006, Pages 3344–3350
نویسندگان
Masaru Watanabe, Toru Iida, Hiroshi Inomata,