کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7642897 | 1494876 | 2015 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A novel hybrid flow-injection/sequential-injection methodology for the rapid evaluation of the total antioxidant capacity of wines using inhibition of the alkaline luminol-potassium permanganate chemiluminescent reaction
ترجمه فارسی عنوان
روش جدید تزریق جریان / تزریق ترکیبی برای ارزیابی سریع کل ظرفیت آنتی اکسیدانی شراب ها با استفاده از مهار واکنش شیمیایی لومینول پتاسیم پرمنگنات
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کلمات کلیدی
ظرفیت آنتی اکسیدان کل، شیمی معدنی، تجزیه و تحلیل تزریق به طور جداگانه، تجزیه و تحلیل تزریق جریان، شراب،
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
چکیده انگلیسی
This work reports the development and validation of a novel hybrid flow injection/sequential injection (FI-SI) method with chemiluminescence (CL) detection for the rapid evaluation of the total antioxidant capacity (TAC) of wines. The method is based on the inhibition of the CL reaction between luminol and potassium permanganate in alkaline medium by the antioxidants in the sample. Zones of sample, potassium permanganate and alkaline luminol were sequentially injected into the carrier stream of the FI-SI manifold. As the zones were delivered to the CL detector, they overlapped and antioxidants in the samples scavenged a portion of potassium permanganate causing a decrease in the CL intensity. The statistical significance of the main chemical and instrumental conditions was studied using a two-level Plackett-Burman experimental design approach and the significant variables were further selected using a univariate approach. The method was validated in terms of linearity, limits of detection (LOD) and quantification (LOQ), accuracy (trueness and precision), matrix effects, and robustness. The linear range for gallic acid (used to express the TAC) was 0.90 μmol Lâ 1-15 μmol Lâ 1, the LOD was 0.30 μmol Lâ 1 and the LOQ was 0.90 μmol Lâ 1. The precision of the method (expressed as the % relative standard deviation) was better than 6.4% and the % recoveries in wines were â¥Â 93%. The proposed FI-SI CL method was compared with the DPPH method for the analysis of 25 wine samples.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Microchemical Journal - Volume 118, January 2015, Pages 223-230
Journal: Microchemical Journal - Volume 118, January 2015, Pages 223-230
نویسندگان
Dimitrios Karampelas, Anastasios Economou, Antony Calokerinos,