کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7643617 | 1494884 | 2013 | 28 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The successive projections algorithm for interval selection in PLS
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: The successive projections algorithm for interval selection in PLS The successive projections algorithm for interval selection in PLS](/preview/png/7643617.png)
چکیده انگلیسی
The successive projections algorithm (SPA) is aimed at selecting a subset of variables with small multi-collinearity and suitable prediction power for use in Multiple Linear Regression (MLR). The resulting SPA-MLR models have advantages in terms of simplicity and ease of interpretation as compared to latent-variable models, such as Partial-Least-Squares (PLS). However, PLS tends to be less sensitive to instrumental noise. The present paper proposes an extension of SPA to combine the noise-reduction properties of PLS with the possibility of discarding non-informative variables in SPA. For this purpose, SPA is modified in order to select intervals of variables for use in PLS. The proposed iSPA-PLS algorithm is evaluated in two case studies involving near-infrared spectrometric analysis of wheat and beer extract samples. As compared to full-spectrum PLS, the resulting iSPA-PLS models exhibited better performance in terms of both cross-validation and external prediction. On the other hand, iSPA-PLS and SPA-MLR presented similar cross-validation performance, but the iSPA-PLS models clearly outperformed SPA-MLR in the external prediction. Such results indicate that iSPA-PLS may be more robust with respect to differences between the external prediction set and the calibration set used in the cross-validation procedure.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Microchemical Journal - Volume 110, September 2013, Pages 202-208
Journal: Microchemical Journal - Volume 110, September 2013, Pages 202-208
نویسندگان
Adriano de Araújo Gomes, Roberto Kawakami Harrop Galvão, Mário Cesar Ugulino de Araújo, Germano Véras, Edvan Cirino da Silva,