کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7668653 | 1495169 | 2018 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
MRCI study on transition dipole moments and transition probabilities of 18 low-lying states of CP+ cation
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
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چکیده انگلیسی
This paper calculates the potential energy curves, spectroscopic parameters, transition dipole moments, and transition probabilities of the PO+ radical. The radiative lifetimes are determined for the vibrational levels of several states. Spectroscopic measurement schemes for observing these states are proposed. The X3Î , 23Î , 13Σâ, 15Î , 25Σ+ and all the six singlet states as well as the first well of the 15Σâ and 15Î states can be observed via the measurement of transitions proposed here. Some difficulties exist when we observe the 13Î and 23Σ+ states, as well as the first well of 15Σ+ state, and the second well of the 13Σ+ state by observing the emissions proposed in this paper. The second well of the 13Σ+, 15Σ+, 15Î, and 15Σâ states are very difficult to observe as almost all the transitions arising from this well are very weak.137
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 200, 5 July 2018, Pages 235-245
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 200, 5 July 2018, Pages 235-245
نویسندگان
Dan Zhou, Kedong Wang, Xue Li,