کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7673064 1495251 2014 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Solvent and structural effects on the UV absorption spectra of N-(substituted phenyl)-2-cyanoacetamides
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Solvent and structural effects on the UV absorption spectra of N-(substituted phenyl)-2-cyanoacetamides
چکیده انگلیسی

- Absorption spectra of selected cyano-acetamides were recorded in 16 solvents.
- Significant shift of the absorption maximum was detected only in DMSO and DMF.
- The effects of solvent were interpreted by Kamlet-Taft LSER concept.
- The effects of substituent were interpreted by Hammett substituent constant.
- The experimental results were interpreted with ab initio method MO calculation.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy - Volume 117, 3 January 2014, Pages 568-575
نویسندگان
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