کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7724626 1497832 2018 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Activating abnormal capacity in stoichiometric NaVO3 as cathode material for sodium-ion battery
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
Activating abnormal capacity in stoichiometric NaVO3 as cathode material for sodium-ion battery
چکیده انگلیسی
Traditional sodium-ion battery cathodes utilize the change in oxidation state of the transition metal(s) in the structure to accommodate the electron transfer during charge and discharge. Recent researches on sodium-rich compounds such as Na2RuO3 and Na2IrO3 suggest that anionic reaction with oxygen can be an additional source of electrons during electrochemical reactions. Here we demonstrate for the first time that stoichiometric NaVO3, despite the valence of vanadium of 5+, delivers a reversible capacity by activating it beyond 4.5 V. Elemental analysis confirms Na removal and insertion from/into NaVO3 during charge/discharge. X-ray photoelectron spectroscopy and X-ray absorption near-edge spectroscopy results show that the oxidation state of vanadium remains unchanged, while oxygen is likely to compensate for the charge transfer during charge/discharge. Theoretical calculation on spin density of electrons in the lattice also supports the involvement of oxygen during sodium removal. Our demonstration of the unique behaviors of NaVO3 provides a new exciting direction for research in sodium-ion battery cathodes.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 400, 1 October 2018, Pages 377-382
نویسندگان
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