کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7724650 | 1497834 | 2018 | 12 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Characterization of behaviour and hazards of fire and deflagration for high-energy Li-ion cells by over-heating
ترجمه فارسی عنوان
مشخص کردن رفتار و خطرات آتش سوزی و پیشگیری از انفجار باتری های لیتیوم با انرژی بالا توسط گرمای بیش از حد
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
چکیده انگلیسی
Fire and deflagration are extreme manifestation of thermal runaway (TR) of Li-ion cells, and they are characterized for fully charged LiNiCoAlO2 (LNCA) 18650â¯cells in this investigation. The cells are over-heated using a cone calorimeter under different incident heat fluxes. When the cells are exposed to the incident heat flux larger than 35â¯kWâ¯mâ2, both fire and deflagration present. The pressure valve opens when the temperature of the cell is higher than 132â¯Â°C. The fire occurs with the valve opening when the concentration of the venting vapour in the air is higher than the lower flammability limit. The deflagration happens after the cell temperature arrives about 200â¯Â°C, and is mainly arising from the cathode decomposition, the combustion of solvents and the anode relevant thermal reactions. The extreme temperatures of the cell and the flame during deflagration are over than 820 and 1035â¯Â°C, respectively. The production of COx, mass loss, heat release rate (HRR) are quantitative identified, and are found increase as the increasing incident heat flux. Based on revised oxygen consumption method, the HRR and liberated heat during the fire and deflagration for the cells are up to 11.8â¯Â±â¯0.05â¯kW and 163.1â¯Â±â¯1.5â¯kJ, respectively.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 398, 15 September 2018, Pages 55-66
Journal: Journal of Power Sources - Volume 398, 15 September 2018, Pages 55-66
نویسندگان
Ping Ping, Depeng Kong, Jiaqing Zhang, Ruoxi Wen, Jennifer Wen,