کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7730723 | 1497938 | 2015 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Electrochemically conductive treatment of TiO2 nanotube arrays in AlCl3 aqueous solution for supercapacitors
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Electrochemically conductive treatment of TiO2 nanotube arrays in AlCl3 aqueous solution for supercapacitors Electrochemically conductive treatment of TiO2 nanotube arrays in AlCl3 aqueous solution for supercapacitors](/preview/png/7730723.png)
چکیده انگلیسی
Highly ordered TiO2 nanotube arrays (NTAs) with excellent stability and large specific surface area make them competitive using as supercapacitor materials. Improving the conductivity of TiO2 is of great concern for the construction of high-performance supercapacitors. In this work, we developed a novel approach to improve the performance of TiO2 materials, involving the fabrication of Al-doped TiO2 NTAs by a simple electrochemical cathodic polarization treatment in AlCl3 aqueous solution. The prepared Al-doped TiO2 NTAs exhibited excellent electrochemical performances, attributing to the remarkably improved electrical conductivity (i.e., from approx. 10 kΩ to 20 Ω). Further analysis showed that Al3+ ions rather than H+ protons doped into TiO2 lattice cause this high conductivity. A MnO2/Al-TiO2 composite was evaluated by cyclic voltammetry, and achieved the specific capacitance of 544 F gâ1, and the Ragone plot of the sample showed a high power density but less reduction of energy density. These results indicate that the MnO2/Al-TiO2 NTAs sample could be served as a promising electrode material for high -performance supercapacitors.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 294, 30 October 2015, Pages 216-222
Journal: Journal of Power Sources - Volume 294, 30 October 2015, Pages 216-222
نویسندگان
Wenjie Zhong, Shangbin Sang, Yingying Liu, Qiumei Wu, Kaiyu Liu, Hongtao Liu,