کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7731154 | 1497939 | 2015 | 12 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Study of the acetonitrile poisoning of platinum cathodes on proton exchange membrane fuel cell spatial performance using a segmented cell system
ترجمه فارسی عنوان
بررسی مسمومیت استونیتریل کاتود پلاتین بر عملکرد مکانی پیل سوختی غشای پروتون تبادل با استفاده از یک سیستم سلولی جدا شده
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
چکیده انگلیسی
Due to the wide applications of acetonitrile as a solvent in the chemical industry, acetonitrile can be present in the air and should be considered a possible pollutant. In this work, the spatial proton exchange membrane fuel cell performance exposed to air with 20Â ppm CH3CN was studied using a segmented cell system. The injection of CH3CN led to performance losses of 380Â mV at 0.2Â AÂ cmâ2 and 290Â mV at 1.0Â AÂ cmâ2 accompanied by a significant change in the current density distribution. The observed local currents behavior is likely attributed to acetonitrile chemisorption and the subsequent two consecutive reduction/oxidation reactions. The hydrolysis of CH3CN and its intermediate imine species resulted in NH4+ formation, which increased the high-frequency resistance of the cell and affected oxygen reduction and performance. Other products of hydrolysis can be oxidized to CO2 under the operating conditions. The reintroduction of pure air completely recovered cell performance within 4Â h at 1.0Â AÂ cmâ2, while at 0.2Â AÂ cmâ2 the cell recovery was only partial. A detailed analysis of the current density distribution, its correlation with spatial electrochemical impedance spectroscopy data, possible CH3CN oxidation/reduction mechanisms and mitigation strategies are presented and discussed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 293, 20 October 2015, Pages 929-940
Journal: Journal of Power Sources - Volume 293, 20 October 2015, Pages 929-940
نویسندگان
Tatyana V. Reshetenko, Jean St-Pierre,