کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7731289 | 1497938 | 2015 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Electrochemical characterization of monoclinic and orthorhombic Li3CrF6 as positive electrodes in lithium-ion batteries synthesized by a sol-gel process with environmentally benign chemicals
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Lithium transition metal fluorides (Li3MF6; MÂ =Â Fe, V) with cryolite structure are investigated as positive electrode materials for lithium-ion batteries. A novel sol-gel process with trifluoroacetic acid as fluorine source was used to synthesize monoclinic and orthorhombic Li3CrF6. A ball milling process with Li3CrF6, binder, and conductive agent was applied to form a Li3CrF6 composite, which was electrochemically characterized against lithium metal for the first time. The electrochemical properties of two different modifications are quite similar, with a reversible specific capacity of 111Â mAhgâ1 for monoclinic Li3CrF6 and 106Â mAhgâ1 for orthorhombic Li3CrF6 (1 eq. Li â 143Â mAhgâ1). The electrochemically active redox couple CrIII/CrII was confirmed by X-ray photoelectron spectroscopy.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 294, 30 October 2015, Pages 444-451
Journal: Journal of Power Sources - Volume 294, 30 October 2015, Pages 444-451
نویسندگان
Georg Lieser, Volker Winkler, Holger GeÃwein, Lea de Biasi, Sven Glatthaar, M.J. Hoffmann, Helmut Ehrenberg, Joachim R. Binder,