کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7731620 | 1497938 | 2015 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Heterogeneous NiCo2O4@polypyrrole core/sheath nanowire arrays on Ni foam for high performance supercapacitors
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A novel heterogeneous NiCo2O4@PPy core/sheath nanowire arrays are directly grown on Ni foam involving three facile steps, hydrothermal synthesis and calcination of NiCo2O4 nanowire arrays and subsequent in-situ oxidative polymerization of polypyrrole (PPy). When investigated as binder- and conductive additive-free electrodes for supercapacitors (SCs) in 6Â M KOH, the NiCo2O4@PPy core/sheath nanowire arrays exhibit high areal capacitance of 3.49Â FÂ cmâ2 at a discharge current density of 5Â mAÂ cmâ2, which is almost 1.5 times as much as the pristine NiCo2O4 (2.30Â FÂ cmâ2). More importantly, it can remain 3.31Â FÂ cmâ2 (94.8% retention) after 5000 cycles. The as-obtained electrode also displays excellent rate capability, whose areal capacitance can still remain 2.79Â FÂ cmâ2 while the discharge current density is increased to 50Â mAÂ cmâ2. The remarkable electrochemical performance is mainly attributed to the unique heterogeneous core/sheath nanowire-array architectures.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 294, 30 October 2015, Pages 120-127
Journal: Journal of Power Sources - Volume 294, 30 October 2015, Pages 120-127
نویسندگان
Jing Hu, Minchan Li, Fucong Lv, Mingyang Yang, Pengpeng Tao, Yougen Tang, Hongtao Liu, Zhouguang Lu,