کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7733703 | 1497952 | 2015 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Improved cycling performance of P2-type layered sodium cobalt oxide by calcium substitution
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Improved cycling performance of P2-type layered sodium cobalt oxide by calcium substitution Improved cycling performance of P2-type layered sodium cobalt oxide by calcium substitution](/preview/png/7733703.png)
چکیده انگلیسی
P2-type Na2/3âxCaxCoO2 is synthesized via a conventional solid-state reaction. The substituted calcium ions occupy the sodium ion layer and eliminate the lattice mismatches of the two phases in Na2/3âxCaxCoO2. Several voltage steps typically observed in the voltage profiles of NaxCoO2 are mostly disappeared associated with the expansion of single-phase regions, because the substituted calcium ions hinder the ordering of sodium ions and vacancies. Furthermore the Na2/3âxCaxCoO2 shows improved cycling performance especially at high charging-discharging rate. During the cycling test, the calcium-free Na0.74CoO2 shows phase separation to form an inactive sodium poor phase, while the Na5/8Ca1/24CoO2 maintained the single phase, suggesting that the calcium substitution suppress the structural change of the P2-type NaxCoO2 to prevent the phase separation, resulting in the improved cycling performance.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 280, 15 April 2015, Pages 205-209
Journal: Journal of Power Sources - Volume 280, 15 April 2015, Pages 205-209
نویسندگان
Masaki Matsui, Fumikazu Mizukoshi, Nobuyuki Imanishi,