کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7736642 | 1497970 | 2014 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Influence of temperature on the electrokinetic properties and power generation efficiency of Nafion® 117 membranes
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
In the present study we investigate the transport properties of Nafion® 117 membranes in temperatures ranging from ambient temperature up to 70 °C. The hydraulic permeability, streaming potential and ion conductivity have been measured as function of temperature in 0.03 M LiCl solutions in purposely designed, non-conductive set-ups. In particular, the apparent activation energies of the processes have been retrieved: 29.4 kJ molâ1, 9.3 kJ molâ1 and 22.9 kJ molâ1 for the hydraulic permeability, streaming potential coefficient and ion conductivity respectively. Based on the knowledge of the temperature dependence of these three independent properties the figure-of-merit of the electrokinetic energy conversion process has been calculated obtaining a monotonous increase of the efficiency with temperature. At 70 °C the electrokinetic efficiency is rather high about 26.6%:50% higher with respect to the one found at room temperature. The electrokinetic transport properties were also used to esteem the average pore size of the water channels in the polymer matrix resulting in pore diameters ranging approximately from 2.0 (25 °C) to 2.8 nm (70 °C).
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 262, 15 September 2014, Pages 192-200
Journal: Journal of Power Sources - Volume 262, 15 September 2014, Pages 192-200
نویسندگان
Jacopo Catalano, Anders Bentien,