کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7737837 | 1497983 | 2014 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Investigation of carbon supported Pd-Cu nanoparticles as anode catalysts for direct borohydride fuel cell
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Carbon supported Pd and bimetallic Pd-Cu nanoparticles with different compositions are prepared by a modified polyol method and used as anode catalysts for direct borohydride fuel cell (DBFC). The physical and electrochemical properties of the as-prepared electrocatalysts are investigated by transmission electron microscopy (TEM), X-ray diffraction (XRD), ICP-AES, cyclic voltammetry (CV), chronoamperometry (CA), and fuel cell experiments. The results show that the carbon supported Pd-Cu bimetallic catalysts have much higher catalytic activity for the direct oxidation of BH4â than the carbon supported pure nanosized Pd catalyst, especially the Pd50Cu50/C catalyst presents the highest catalytic activity among all as-prepared catalysts, and the DBFC using Pd50Cu50/C as anode catalyst and Pt/C as cathode catalyst gives the best performance, and the maximum power density is 98 mW cmâ2 at a current density of 223 mA cmâ2 at 60 °C.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 249, 1 March 2014, Pages 239-246
Journal: Journal of Power Sources - Volume 249, 1 March 2014, Pages 239-246
نویسندگان
Gamze Behmenyar, AyÅe Nilgün Akın,