کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7738096 1497981 2014 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Superior cycle stability and high rate capability of Zn-Al-In-hydrotalcite as negative electrode materials for Ni-Zn secondary batteries
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
Superior cycle stability and high rate capability of Zn-Al-In-hydrotalcite as negative electrode materials for Ni-Zn secondary batteries
چکیده انگلیسی
Zn-Al-In layered double hydroxides (LDHs) are synthesized by hydrothermal method and investigated as negative electrode materials for Ni-Zn batteries. The Fourier transform infrared spectra (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) images show the as-prepared samples are well-crystallized and hexagon structure. The electrochemical performances of Zn-Al-LDHs and Zn-Al-In-LDHs with different Zn/Al/In molar ration are investigated by the cyclic voltammograms (CV), Tafel polarization and galvanostatic charge-discharge measurements. Zn-Al-LDHs shows good stability in the first 300-cycles. However, during the subsequent cycles, the discharge capacity decreases with increasing of the cycles. Compared with Zn-Al-LDHs, Zn-Al-In-LDHs with different Zn/Al/In molar rations, especially the sample of Zn/Al/In = 3:0.75:0.25 (molar ration) have higher discharge capacity and more stable cycling performances. This battery can undergo at least 800 charge-discharge cycles at constant current of 1C without dendrite and short circuits. The discharge capacity of Zn-Al-In-LDHs after the 800th cycle remains about 380 mAh g−1. Zn-Al-In-LDHs possess a high rate capability to meet the needs of high-storage applications.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 251, 1 April 2014, Pages 344-350
نویسندگان
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