کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7740435 | 1497989 | 2013 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Charge/discharge performances of glyme-lithium salt equimolar complex electrolyte for lithium secondary batteries
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
The electrochemical and battery performances of a CH3-O-(C2H4O)3-CH3/LiN(SO2CF3)2 1:1 equimolar complex electrolyte were evaluated using [Li metal|Li metal], [LiFePO4|Li metal], and [LiNi1/3Mn1/3Co1/3O2|Li metal] cells. A relatively favorable surface was formed at the Li metal/electrolyte interface revealed by observation of the storage time dependence of the electrochemical impedance spectroscopy. A 3V-class [LiFePO4|Li metal] cell exhibited favorable capacity retention with little degradation after 600 cycles (2.5-4.0Â V). A 4V-class [LiNi1/3Mn1/3Co1/3O2|Li metal] cell also exhibited good capacity retention of approximately 60% of the initial discharge capacity after 400 cycles (2.7-4.2Â V), while the capacity retention decreased markedly upon increasing the upper charge cutoff voltage above 4.4Â V.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 243, 1 December 2013, Pages 323-327
Journal: Journal of Power Sources - Volume 243, 1 December 2013, Pages 323-327
نویسندگان
Shiro Seki, Nobuyuki Serizawa, Katsuhito Takei, Kaoru Dokko, Masayoshi Watanabe,