کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7740587 1497992 2013 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
In-situ neutron diffraction study of the xLi2MnO3·(1 − x)LiMO2 (x = 0, 0.5; M = Ni, Mn, Co) layered oxide compounds during electrochemical cycling
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
In-situ neutron diffraction study of the xLi2MnO3·(1 − x)LiMO2 (x = 0, 0.5; M = Ni, Mn, Co) layered oxide compounds during electrochemical cycling
چکیده انگلیسی
The layered oxide compounds xLi2MnO3·(1 − x)LiMO2 (M = Ni, Mn, Co) are of great interest as positive electrode materials for high energy density lithium-ion batteries. In-situ neutron diffraction was carried out to compare the structural changes between the classical layered compound Li[Ni1/3Mn1/3Co1/3]O2 (x = 0) and lithium-excess layered compound Li[Li0.2Ni0.18Mn0.53Co0.1]O2 (x = 0.5) during electrochemical cycling. In this work, lab made pouch cells were built for the in-situ study and graphite was used as the anode material. Irreversible structural change of Li[Li0.2Ni0.18Mn0.53Co0.1]O2 during first charge (4.7 V)/discharge cycle (2.0 V) was indicated by dynamic changes in lattice d-spacing, while the Li[Ni1/3Mn1/3Co1/3]O2 showed completely reversible structural evolution between 4.4 V and 2.5 V. Ex-situ neutron powder diffraction was performed on both pristine and chemically delithiated lithium-excess layered compounds to better understand the irreversible structure change.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 240, 15 October 2013, Pages 772-778
نویسندگان
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