کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7740799 1497991 2013 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Beneficial effects of activated carbon additives on the performance of negative lead-acid battery electrode for high-rate partial-state-of-charge operation
ترجمه فارسی عنوان
اثرات سودمند افزودنی کربن فعال بر عملکرد الکترود باتری منفذ سرب منجر به کارکرد با مقدار زیاد حالت باتری
کلمات کلیدی
افزودنی کربن فعال، صفحه منفی، باتری سربی - اسیدی، نرخ باالی نرخ دولتی، سولفات،
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
چکیده انگلیسی
Experiments are made with negative electrode of 2 V cell and 12 V lead-acid battery doped with typical activated carbon additives. It turns out that the negative electrode containing tens-of-micron-sized carbon particles in NAM exhibits markedly increased HRPSoC cycle life than the one containing carbon particles with much smaller size of several microns or the one containing no activated carbon. The improved performance is mainly attributed to the optimized NAM microstructure and the enhanced electrode reaction kinetics by introducing appropriate activated carbon. The beneficial effects can be briefly summarized from three aspects. First, activated carbon acts as new porous-skeleton builder to increase the porosity and active surface of NAM, and thus facilitates the electrolyte diffusion from surface to inner and provides more sites for crystallization/dissolution of lead sulfate; second, activated carbon plays the role of electrolyte supplier to provide sufficient H2SO4 in the inner of plate when the diffusion of H2SO4 from plate surface cannot keep pace of the electrode reaction; Third, activated carbon acts as capacitive buffer to absorb excess charge current which would otherwise lead to insufficient NAM conversion and hydrogen evolution.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 241, 1 November 2013, Pages 150-158
نویسندگان
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