کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7740903 | 1497991 | 2013 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The electrochemical behaviors of Zn-Al-La-hydrotalcite in Zn-Ni secondary cells
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Zn-Al-La-CO3 layered double hydroxides (LDHs) are prepared by the constant pH co-precipitation method and proposed as a novel anodic material in Zinc-Nickel secondary cells. The X-ray diffraction (XRD) patterns and scanning electron microscopy (SEM) images reveal that the as-prepared samples are well-crystallized and hexagon layer structure. Electrochemical performances of Zn-Al-La-hydrotalcites with different Zn/Al/La molar ratios are investigated by galvanostatic charge-discharge measurements, cyclic voltammograms (CV) and Tafel polarization curves. In comparison with the Zn-Al-hydrotalcite, Zn-Al-La-hydrotalcites with different Zn/Al/La molar ratios have more stable cycling performance. After 400 cell cycles, Zn-Al-La-LDH with Zn/Al/La = 3:0.8:0.2 retains specific discharge capacity of 297 mAh gâ1 with a retention rate of 79.0%, which is much superior to that of 205 mAh gâ1 with a retention rate of 53.5% for the Zn-Al-La-LDH with Zn/Al/La = 3:0.9:0.1 and 241 mAh gâ1 with a retention rate of 69.0% for the Zn-Al-La-LDH with Zn/Al/La = 3:0.6:0.4. The results demonstrate that the Zn-Al-La-LDH with Zn/Al/La = 3:0.8:0.2 has the best reversible cycling behavior. The CV exhibits well reversibility and the Tafel polarization curves reveal more positive corrosion potential for Zn-Al-La-hydrotalcite.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 241, 1 November 2013, Pages 404-409
Journal: Journal of Power Sources - Volume 241, 1 November 2013, Pages 404-409
نویسندگان
Xinming Fan, Zhanhong Yang, Xiaoe Xie, Wei Long, Ruijuan Wang, Zhilin Hou,