کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7744433 | 1498224 | 2018 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Pd-doped La0.6Sr0.4Co0.2Fe0.8O3âδ perovskite oxides as cathodes for intermediate temperature solid oxide fuel cells
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The effects of palladium doping on the catalytic activity of La0.6Sr0.4Co0.2Fe0.8O3âδ(LSCF) cathodes are investigated by comparing the performance of La0.6Sr0.4Co0.2Fe0.8âxPdxO3âδ (LSCFPd) cathodes with different doping content and LSCF cathodes. The electrochemical results show that Pd doping decreases the polarization resistance and promotes the catalytic activity of LSCF cathodes. This promotion becomes greater with the increase of Pd doping content, which is also reflected by electrical conductivity relaxation (ECR) measurement results because the oxygen surface exchange coefficient of LSCFPd is improved by Pd doping. According to the in-situ high temperature XRD and TG-DSC results, perovskite LSCFPd materials are stable at temperature below 700â¯Â°C, and some Pd species are segregated during heating process.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Ionics - Volume 319, June 2018, Pages 22-27
Journal: Solid State Ionics - Volume 319, June 2018, Pages 22-27
نویسندگان
Feng Zhou, Lihong Zhou, Mingyao Hu, Xin Tong, Yihui Liu, Haizhao Li, Shengbing Yang, Mingrui Wei,