کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7745248 | 1498255 | 2016 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis, structure, and electrochemical properties of crystalline Li-P-S-O solid electrolytes: Novel lithium-conducting oxysulfides of Li10GeP2S12 family
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Synthesis, structure, and electrochemical properties of crystalline Li-P-S-O solid electrolytes: Novel lithium-conducting oxysulfides of Li10GeP2S12 family Synthesis, structure, and electrochemical properties of crystalline Li-P-S-O solid electrolytes: Novel lithium-conducting oxysulfides of Li10GeP2S12 family](/preview/png/7745248.png)
چکیده انگلیسی
Novel lithium-ion (Li+)-conducting oxysulfides of the Li10GeP2S12 family were found in the ternary Li2S-P2S5-P2O5 system; Li10GeP2S12-type solid solutions with compositions Li3 + 5xP1 â xS4 â zOz (x = 0.03-0.08, z = 0.4-0.8) were confirmed. The solid solutions showed ionic conductivities from 4.14 Ã 10â 5 to 2.64 Ã 10â 4 S cmâ 1 at 298 K and a wide electrochemical window of 0-5.0 V (vs. Li/Li+). Among the solid solutions synthesized, the purest phase had the composition Li3.35P0.93S3.5O0.5 (x = 0.07, z = 0.5). Structural analysis revealed that the novel oxysulfides are isostructural to the original Li10GeP2S12 structure and the (P/â¡)(S/O)4 tetrahedra, which indicates the presence of cation defects with oxygen substitution in the crystal structure. Electrochemical stability of the oxysulfides was confirmed in the voltage range of 0-5.0 V. The solid-electrolyte interphase (SEI) resistivity and its cycle-dependence evaluation for new materials demonstrated that the oxysulfides had lower resistivities and furnished well-contacted SEI layers during the charge-discharge process.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Ionics - Volume 288, May 2016, Pages 229-234
Journal: Solid State Ionics - Volume 288, May 2016, Pages 229-234
نویسندگان
Kota Suzuki, Masamitsu Sakuma, Satoshi Hori, Tetsuya Nakazawa, Miki Nagao, Masao Yonemura, Masaaki Hirayama, Ryoji Kanno,