کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7745258 1498255 2016 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Effect of surface modification and oxygen deficiency on intercalation property of lithium nickel manganese oxide in an all-solid-state battery
موضوعات مرتبط
مهندسی و علوم پایه شیمی الکتروشیمی
پیش نمایش صفحه اول مقاله
Effect of surface modification and oxygen deficiency on intercalation property of lithium nickel manganese oxide in an all-solid-state battery
چکیده انگلیسی
LiNbO3-coated LiNi0.5Mn1.5O4 powders were synthesized by a sol-gel method, and their intercalation property as a cathode material was investigated using all-solid-state batteries with Li10GeP2S12 solid electrolyte and In-Li metal anode. The LiNbO3 coating delivered reversible lithium intercalation of LiNi0.5Mn1.5O4 through an electrochemical interface with the Li10GeP2S12. Oxygen-deficient LiNi0.5Mn1.5O4−δ with a higher electronic conductivity than LiNi0.5Mn1.5O4 improved the intercalation activity. An all-solid-state battery consisting of 3 wt.%-LiNbO3-coated LiNi0.5Mn1.5O4−δ/Li10GeP2S12/In-Li exhibited a discharge capacity of 80 mAh g− 1 at the first cycle with an average discharge voltage of 4.1 V (vs. In-Li), which demonstrates the possibility of 5 V class all-solid-state batteries with a high voltage spinel cathode.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Ionics - Volume 288, May 2016, Pages 244-247
نویسندگان
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