کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7746384 | 1498280 | 2014 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Oxygen isotope labeling method and oxygen reduction reaction mechanism of an SOFC cathode
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
Combined isotope-exchange and electrochemical experiments have been carried out to study the oxygen reduction reaction of a solid oxide fuel cell cathode under different operation conditions. For a test cell, LaNi0.6Fe0.4O3 (LNF) is chosen as a porous cathode material which was sintered on an Y2O3-ZrO2 electrolyte with a Ce0.9Gd0.1O1.95 interlayer. Comparisons are made in the isotope oxygen diffusion profiles between an OCV and a polarized (JÂ =Â 0.07 A/cm2) conditions by taking into account the oxygen diffusion and surface exchange properties of bulk LNF as well as accumulated results on oxygen isotope profiles. Considerations have been made to account for the concentration up-hill diffusion in the GDC interlayer under the OCV conditions and other characteristic features, leading to recognition that the oxygen reduction reaction in the perovskite cathode and GDC interlayer exhibits complicated behaviors caused probably by several different mechanisms.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Ionics - Volume 262, 1 September 2014, Pages 392-397
Journal: Solid State Ionics - Volume 262, 1 September 2014, Pages 392-397
نویسندگان
Mina Nishi, Harumi Yokokawa, Haruo Kishimoto, Katsuhiko Yamaji, Teruhisa Horita,