کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7746438 | 1498280 | 2014 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effect of polarization on Sr and Zr diffusion behavior in LSCF/GDC/YSZ system
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
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چکیده انگلیسی
To accurately evaluate the role as diffusion barrier of gadolinia-doped ceria (GDC) interlayer, often used in real stacks of solid oxide fuel cells, the cation diffusion behavior in a LSCF/GDC/YSZ system was investigated. Diffusion under open circuit voltage (OCV) and cathodic polarization conditions was evaluated using pellet-type cells in which a dense GDC interlayer, about 1 μm in thickness, was prepared by pulse laser deposition (PLD). Results clearly show that under polarization, SrZrO3 formation along both LSCF/GDC and GDC/YSZ interfaces is accelerated. The enhancement of Sr diffusion during cathodic polarization is explained by a shift to higher values of the thermodynamic activity of Sr at the LSCF/GDC interface that also leads to a decrease in oxygen potential.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Ionics - Volume 262, 1 September 2014, Pages 454-459
Journal: Solid State Ionics - Volume 262, 1 September 2014, Pages 454-459
نویسندگان
Fangfang Wang, Manuel E. Brito, Katsuhiko Yamaji, Do-Hyung Cho, Mina Nishi, Haruo Kishimoto, Teruhisa Horita, Harumi Yokokawa,