کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7746611 | 1498288 | 2014 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Enhancement of low-temperature performance of LiFePO4 electrode by butyl sultone as electrolyte additive
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Enhancement of low-temperature performance of LiFePO4 electrode by butyl sultone as electrolyte additive Enhancement of low-temperature performance of LiFePO4 electrode by butyl sultone as electrolyte additive](/preview/png/7746611.png)
چکیده انگلیسی
Low-temperature performance of a LiFePO4 electrode is successfully and easily improved by adding butyl sultone (BS) in 1 mol Lâ 1 LiPF6-ethylene carbonate (EC)/propylene carbonate (PC)/ethyl methyl carbonate (EMC) (1:1:3 vol.%) electrolyte. Through BS addition, discharge capacity and rate performance at low temperature are obviously enhanced. The surface morphology and chemical composition of the solid electrolyte interphase (SEI) formed on the surface of the LiFePO4 electrode are studied through scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) analysis, and combined with the electrochemical impedance spectrum (EIS) analysis, the improved low-temperature performance is attributed to participating in the formation of a thinner SEI film, which enhances the ion conductivity of the SEI film and accelerates the migration of lithium ions through the SEI film.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Ionics - Volume 254, January 2014, Pages 27-31
Journal: Solid State Ionics - Volume 254, January 2014, Pages 27-31
نویسندگان
Lixia Liao, Tao Fang, Xiaoguang Zhou, Yunzhi Gao, Xinqun Cheng, Lingling Zhang, Geping Yin,