Electric properties and internal dynamics of the [C6H18N2] SbCl5 [C6H18N2] Cl2 in intermediate temperature phase (part II)

The electrical properties of a new molecular-ionic complex [C6H18N2]2 SbCl5 Cl2 were studied in the temperature range 293 K-418 K. The internal dynamics of protons of [C6H18N2] SbCl5 [C6H17N2] Cl2 were studied by 1H NMR method. Below 393 K the Grotthus type mechanism of proton transport models the conductivity of studied [C6H17N2] SbCl5 [C6H17N2] Cl2 crystal i.e. diffusion of protons and turn of the cation around the pseudo C3 axis take place. The favoured type of conductivity in complex under study is the protonic ones.