کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7833173 1503516 2018 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Monolithic Mn/Ce-based catalyst of fibrous ceramic membrane for complete oxidation of benzene
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
Monolithic Mn/Ce-based catalyst of fibrous ceramic membrane for complete oxidation of benzene
چکیده انگلیسی
Herein, a series of monolithic Mn/Ce-based catalyst of ceramic membranes (CMs) were prepared through impregnation method for volatile organic compounds (VOCs) removal. The porous fibrous CMs with a sinter-locked network structure were fabricated by molding method in a feasible sintering process. Then, the catalytic CMs were systematically analyzed by using specific analytical techniques. The results showed that the fibrous CMs possessed a unique interconnected and uniform pore structure, and MnOx-CeO2 active phases were homogenously dispersed into the porous CMs support. The catalytic activity of samples was measured by using benzene as target VOCs. The results revealed that all catalytic CMs were active for oxidation of benzene. Significantly, the catalytic performance was promoted by introducing Ce species into MnOx. Among all, MnOx-CeO2-3:1 catalyst exhibited the lowest 90% benzene conversion temperature (T90) at 244 °C and high stability with continuous benzene stream in the presence of 90 vol.% (20 °C) water vapor under a gaseous hourly space velocity (GHSV) of 5000 h−1, owing to the lower-temperature reducibility and the abundant active oxygen (OAds.) with synergetic effect of MnOx and CeO2. The results indicated a promising way to design a high efficiency dual functional CMs for the industrial application of removal VOCs while controlling particulate matters (PMs) from hot gases.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Surface Science - Volume 456, 31 October 2018, Pages 594-601
نویسندگان
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