کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7833899 | 1503523 | 2018 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Enhanced photocatalytic degradation and hydrogen production activity of in situ grown TiO2 coupled NiTiO3 nanocomposites
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Enhanced photocatalytic degradation and hydrogen production activity of in situ grown TiO2 coupled NiTiO3 nanocomposites Enhanced photocatalytic degradation and hydrogen production activity of in situ grown TiO2 coupled NiTiO3 nanocomposites](/preview/png/7833899.png)
چکیده انگلیسی
A UV and visible light responsive binary phase TiO2 coupled NiTiO3 nanocomposites were prepared by a facile co-precipitation method followed by calcination at elevated temperatures. The phase structure, morphology and optical properties of the nanocomposite were characterized by XRD, FE-SEM, HRTEM, UV-vis DRS, EIS and Raman spectra. XRD and Raman spectrum shows that between 650â¯Â°C and 850â¯Â°C, a phase transition takes place. FE-SEM and TEM analysis revealed that during the synthesis, growth of cylindrical shaped amorphous NiTiO3 took place and upon calcinations; it transforms into highly crystalline interlinked chain type morphology. A noticeable three distinct optical transitions corresponding to 3.1, 2.5 and 2.27â¯eV were observed by UV-vis diffuse reflection spectroscopy (DRS). The TiO2/NiTiO3 nanocomposite was used for Tetracycline and RhB photodegradation, and photocatalytic water splitting activity under UV-vis light irradiation. The results of this study showed that the nanocomposites calcined at 750â¯Â°C exhibit significantly higher photocatalytic degradation and water splitting activity. Based on the experimental results, an n-n heterojunction charge carrier transfer and separation mechanism is proposed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Surface Science - Volume 449, 15 August 2018, Pages 790-798
Journal: Applied Surface Science - Volume 449, 15 August 2018, Pages 790-798
نویسندگان
Sandeep Kumar Lakhera, Hafeez Yusuf Hafeez, Pandiyarasan Veluswamy, V. Ganesh, Anish Khan, Hiroya Ikeda, Bernaurdshaw Neppolian,