کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7846545 | 1508612 | 2017 | 16 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Cis- and trans-perfluorodecalin: Infrared spectra, radiative efficiency and global warming potential
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
طیف سنجی
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چکیده انگلیسی
Perfluorodecalin (PFD) is a molecule used in various medical applications for its capacity to dissolve gases. This potent greenhouse gas was detected for the first time in the atmosphere in 2005. We present infrared absorption cross-section spectra of a pure vapour of cis- and trans-perfluorodecalin at a resolution of 0.1Â cmâ1. Measurements were performed in the 560-3000Â cmâ1 spectral range using Fourier transform spectroscopy. The spectra have been compared with previous experimental data and theoretical calculations by density functional theory. The new experimental absorption cross-sections have been used to calculate a lifetime-corrected radiative efficiency at 300Â K of 0.62Â WÂ mâ2Â ppbâ1 and 0.57Â W.mâ2.ppbâ1 for the cis and trans isomers respectively. This leads to a 100-year time horizon global warming potential of 8030 for cis-PFD and 7440 for trans-PFD.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Quantitative Spectroscopy and Radiative Transfer - Volume 203, December 2017, Pages 538-541
Journal: Journal of Quantitative Spectroscopy and Radiative Transfer - Volume 203, December 2017, Pages 538-541
نویسندگان
Karine Le Bris, Jasmine DeZeeuw, Paul J. Godin, Kimberly Strong,