کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7885964 | 1509785 | 2018 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Role of Cu and Y in sintering, phase transition, and electrical properties of BCZT lead-free piezoceramics
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Lead-free (Ba0.85Ca0.15)(Ti0.9Zr0.1)O3-xwt%CuOywt%Y2O3 (BCZT-CuxYy) ceramics with high piezoelectricity were synthesized by the conventional solid-state reaction method. The role of Cu and Y (Cu/Y) in sintering, phase transition, and electrical properties of such ceramics was systematically studied. The results indicated that the sintering temperatures of BCZT-CuxYy decreased by at least 100â¯Â°C due to the low melting point of CuO. The promotion effect of Cu/Y on phase transition lied in the improvement of TC by 5-15â¯Â°C and the coexistence of O+T phase near room temperature. The contribution of Cu/Y to electrical properties was mainly ascribed to the grains growth, the formed oxygen vacancies and lattice distortions, and the donor doping effect of Y3+. Adding 0.10â¯wt% Cu2+ and 0.06â¯wt% Y3+ into BCZT dramatically improved the electrical properties as following: d33 =â¯552 pC/N, εm =â¯10175, εr =â¯4546, tanδ =â¯0.016, TC =â¯100â¯Â°C, kp =â¯0.475, Qm =â¯157.2, Pr =â¯10.82 μC/cm2 and EC =â¯2.33â¯kV/cm. A plausible mechanism was obtained to explain the reaction process and the favorable performances of BCZT-CuxYy. Co-doping Cu2+ and Y3+ into BCZT could be a promising method to improve and balance the sintering, phase transition, and electrical properties for potential practical applications of lead-free piezoceramics.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 44, Issue 13, September 2018, Pages 15001-15009
Journal: Ceramics International - Volume 44, Issue 13, September 2018, Pages 15001-15009
نویسندگان
Yinghong Wu, Fei Ma, Jingkui Qu, Yang Luo, Jing Song, Guangye Wei, Yingchun Zhang, Tao Qi,