The formation and properties of Sialon-ZrN composites produced by reaction bonding combined with post gas-pressure sintering

Sialon-ZrN composites have been fabricated by a combination of reaction bonding and post-gas-pressure sintering. Composites with different amount of ZrN were post sintered at 1600, 1700 and 1800 °C under a nitrogen pressure of 0.7 MPa for 6 h. The results showed that mass loss due to decomposition increased with increasing sintering temperature. The mass loss at 1600 and 1700 °C was comparable, and below 3% even for the highest ZrN content of 50 wt%, but ranged between 6% and 9% for samples post sintered at 1800 °C with 10-50 wt% ZrN. Composites sintered at 1700 °C had the highest relative density (> 97%) and lowest open porosity (< 2%), and this was independent of ZrN content. The incorporation of the ZrN particles was observed to have an effect on the mechanical properties of the composites. The highest hardness (16.05 ± 0.17 GPa) was observed for the composite sintered at 1700 °C with 20 wt% ZrN but decreased with higher ZrN contents, due to a weak bonding between the ZrN particles and the Sialon matrix. The fracture toughness showed a continuous increase with increasing ZrN content, due to the effect of the weak bonding on toughening mechanisms such as crack branching, crack deflection and crack bridging. The highest fracture toughness (5.35 ± 0.18 MPa m1/2) was observed for the composited sintered at 1700 °C with 50 wt% ZrN.