کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7887485 | 1509790 | 2018 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Improvement of Al3+ ion conductivity by F doping of (Al0.2Zr0.8)4/3.8NbP3O12 solid electrolyte for mixed potential NH3 sensors
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
New Al3+ ion conducting solid electrolytes (Al0.2Zr0.8)4/3.8NbP3O12-xF2x(0â¯â¤xâ¯â¤â¯0.4) with Nasicon-structure are successfully prepared by solid state reaction method. The influences of the doped F- content on the properties of the (Al0.2Zr0.8)4/3.8NbP3O12-xF2x samples are investigated using X-ray powder diffraction (XRD), scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS) and electrochemical impedance spectroscopy (EIS). The results show that F- doping can effectively improve the sinterability and the total conductivity of the (Al0.2Zr0.8)4/3.8NbP3O12-xF2x samples. Among the solids series, (Al0.2Zr0.8)4/3.8NbP3O11.7F0.6 shows the highest conductivity of 1.53â¯Ãâ¯10â3 Sâ¯cmâ1at 500â¯Â°C, which is approximately 7.9 times higher than that of the undoped (Al0.2Zr0.8)4/3.8NbP3O12. The ion transference number of the samples is higher than 0.99 at 300-700â¯Â°C. On the basis of the promising properties, a mixed-potential type NH3 sensor based on (Al0.2Zr0.8)4/3.8NbP3O11.7F0.6 electrolyte and In2O3 sensing electrode has been developed. The sensing performance of the sensor is evaluated. The mixed-potential type sensor can work at relatively low temperatures of 200-350â¯Â°C and an excellent sensitivity of 99.71â¯mV/decade at 250â¯Â°C is obtained. The sensor also displays excellent stability and reproducibility, accompanied by low cross-sensitivities to CO2, CH4 and H2.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 44, Issue 8, 1 June 2018, Pages 8983-8991
Journal: Ceramics International - Volume 44, Issue 8, 1 June 2018, Pages 8983-8991
نویسندگان
Ling Wang, Ce Gao, Lei Dai, Huizhu Zhou, Yuehua Li, Wei Meng, Zhangxing He, R.V. Kumar,