کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7887745 | 1509792 | 2018 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effects of argon sintering atmosphere on luminescence characteristics of Ca6BaP4O17:Sm3+ phosphors
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Effects of argon sintering atmosphere on luminescence characteristics of Ca6BaP4O17:Sm3+ phosphors Effects of argon sintering atmosphere on luminescence characteristics of Ca6BaP4O17:Sm3+ phosphors](/preview/png/7887745.png)
چکیده انگلیسی
In this paper, Ca6BaP4O17:Sm3+ and Li+ co-doped Ca6BaP4O17:Sm3+ phosphors were synthesized in air and argon atmospheres using a solid-state reaction method. The phosphor morphologies and crystal structure were studied using scanning electron microscopy and X-ray diffraction, respectively. The emission and absorption characteristics were investigated using photoluminescence emission spectroscopy and diffuse reflectance spectroscopy. The surface states and composition of phosphor were investigated using X-ray photoelectron spectroscopy. The emission integrated intensities of the phosphors sintered in an argon atmosphere increased 3.5 fold than the ones sintered in air atmosphere, with Li+ ions becoming embedded in the lattice of the Ca6BaP4O17:Sm3+ phosphor. This occurs because there are fewer defect/oxygen vacancies and less of the secondary phase forms, leading to better Sm3+ emission. The results suggest that sintering a mixture of the raw materials of a phosphor in an argon atmosphere is a good approach for synthesizing Ca6BaP4O17:Sm3+ phosphor powders. The color purity and CIE values of an optimized phosphor sample sintered in an argon atmosphere with an Li+ ion compensator were calculated to be ~ 99.6% and (0.612,0.386) in the orange-red region under 405-nm excitation, respectively. Moreover, the solid solubility of Sm3+ ions in the Ca6BaP4O17 host can be enhanced by using an argon atmosphere in the synthesis process.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 44, Issue 6, 15 April 2018, Pages 6278-6284
Journal: Ceramics International - Volume 44, Issue 6, 15 April 2018, Pages 6278-6284
نویسندگان
Chung-Hao Chiang, Hsiu-Hsien Su, Ying-Chien Fang, Sheng-Yuan Chu,