کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7888156 1509793 2018 37 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Surface modification-based three-phase nanocomposites with low percolation threshold for optimized dielectric constant and loss
ترجمه فارسی عنوان
نانوکامپوزیتهای سه فاز مبتنی بر اصلاح سطح با آستانه نفوذ پائین برای ثابت و از دست دادن دی الکتریک بهینه شده
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
چکیده انگلیسی
Integration of the excellent attributes of high dielectric constant and low dielectric loss in flexible polymer-based nanocomposites has attracted increased research attention because of their extensive applications in modern electronic and electric industry. In this study, to obtain the optimized dielectric constant and loss, the fabrication and properties of a three-phase nanocomposites, including poly(vinylidene fluoride) (PVDF) and two nanofillers, namely, surface-modified multi-wall carbon nanotubes (mCNTs) and barium titanate nanoparticles (mBTs), are investigated in detail. The mCNTs and mBTs were obtained via the hydrolysis of 3-aminopropyltriethoxysilane (AMEO) and condensation reactions between the AMEO and nanofillers. The three-phase nanocomposites are fabricated by a phase-separation and hot-pressing process. The mCNTs and mBTs can be uniformly dispersed within the PVDF polymer matrix because of the enhanced hydrogen bonding interaction and compatibility with the polymer matrix. The percolation threshold (as low as 0.50 vol%) of the two-phase mCNTs/PVDF nanocomposites is adopted to optimize the dielectric properties of the three-phase mCNTs/mBTs/PVDF nanocomposites. At the frequency of 102 Hz, a high dielectric constant of 109 and low loss of 0.06 are obtained for the three-phase nanocomposites with only 0.41 vol% mCNTs and 2.8 vol% mBTs, respectively. Meanwhile, owing to the low percolation threshold and enhanced surface compatibility between the nanofillers and PVDF, the tensile strength of the three-phase nanocomposites is greater than that of PVDF by a factor of greater than 1.5. Owing to their high dielectric constant, low dielectric loss and good mechanical properties, these PVDF-based ternary nanocomposites show potential for applications in electronic devices and energy storage systems.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 44, Issue 5, 1 April 2018, Pages 4835-4844
نویسندگان
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