کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7888338 1509794 2018 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Modification of grain boundary structure of SrTiO3 using hydroxyl additives
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Modification of grain boundary structure of SrTiO3 using hydroxyl additives
چکیده انگلیسی
Strontium titanate (SrTiO3) is a typical perovskite material due to its crucial properties such as a good dielectric constant and favorable conductivity. Early studies reported that hydroxyl (OH) groups can manipulate the shape of the SrTiO3 surface and control the crystal growth by changing the surface energy. This concept may be used to increase the population of (111) surfaces to form more Σ3 grain boundaries, which have lower energy for high ionic conductivity. In this study, two common OH additives, glycerol and 1,2-propanediol, were used for preparation of SrTiO3 powders. SrTiO3 powders were synthesized by spray pyrolysis and then sintered to form polycrystalline SrTiO3. The results showed that the additive-treated SrTiO3 powders had a higher population of (111) planes and exhibited higher conductivity than did un-treated powder. In addition, the highest population of Σ3 grain boundaries was generated by 1,2-propanediol treatment (11.0 ± 0.8%) of SrTiO3, followed by glycerol treatment (10.0 ± 0.3%) and no treatment (2.5 ± 0.2%), respectively.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 44, Issue 4, March 2018, Pages 3960-3965
نویسندگان
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