کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7894726 | 1509989 | 2016 | 12 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Corrosion mitigation via a pH stabilization method in monoethanolamine-based solutions for post-combustion CO2 capture
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A pH stabilization method was investigated to mitigate corrosion in aqueous 5Â M monoethanolamine for post-combustion CO2 capture. The room temperature pH of a naturally aerated CO2-loaded solution (i.e., 9.7) was adjusted with NaHCO3 powders to 9.3 and 9.1, and its effect on corrosion of A106 carbon steel was studied. Lower pH initially accelerated corrosion but promoted protective FeCO3 layer formation and subsequently A106 passivation (i.e., Fe3O4 formation). Dissolved oxygen also played a pivotal role by functioning as an additional oxidizer, retarding FeCO3 formation via preferentially oxidizing Fe2+ to form rust, and promoting passivation of A106 under the FeCO3 layer.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Corrosion Science - Volume 106, May 2016, Pages 281-292
Journal: Corrosion Science - Volume 106, May 2016, Pages 281-292
نویسندگان
Liangfu Zheng, James Landon, Naser S. Matin, Gerald A. Thomas, Kunlei Liu,