کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7896401 | 1510020 | 2013 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Electrochemical and XPS studies of the corrosion inhibition of carbon steel in hydrochloric acid pickling solutions by 3,5-bis(2-thienylmethyl)-4-amino-1,2,4-triazole
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Corrosion inhibition of carbon steel in normal hydrochloric acid solution at 30 °C by new 4-amino-1,2,4-triazole derivative, namely 3,5-bis(2-thienylmethyl)-4-amino-1,2,4-triazole (2-TMAT) has been studied by electrochemical impedance spectroscopy (EIS) and polarization techniques. The experimental results have showed that this organic compound revealed a good corrosion inhibition and that the inhibition efficiency is increased with the inhibitor concentration. Two time constants determined by the charge-transfer and the adsorption of the inhibitor, respectively, can be readily outlined. Potentiodynamic polarization showed that 2-TMAT is a mixed type of inhibitor. The adsorption of 2-TMAT on the carbon steel surface in 1 M HCl solution obeyed to the Langmuir isotherm with a very high negative value of the standard Gibbs free energy of adsorption ÎGads° (chemisorption). X-ray photoelectron spectroscopy (XPS) analyses were carried out to establish the mechanism of corrosion inhibition of carbon steel in 1 M HCl medium by 3,5-bis(2-thienylmethyl)-4-amino-1,2,4-triazole (2-TMAT).
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Corrosion Science - Volume 75, October 2013, Pages 123-133
Journal: Corrosion Science - Volume 75, October 2013, Pages 123-133
نویسندگان
M. Tourabi, K. Nohair, M. Traisnel, C. Jama, F. Bentiss,