کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | ترجمه فارسی | نسخه تمام متن |
---|---|---|---|---|---|
7901742 | 1510435 | 2015 | 8 صفحه PDF | سفارش دهید | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The glass transition in high-density amorphous ice
ترجمه فارسی عنوان
انتقال شیشه ای در یخ انحصاری با چگالی بالا
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کلمات کلیدی
انتقال شیشه، یخ آمورف با چگالی بالا، طیف سنجی آرامبخش دی الکتریک، کالریمتری اسکن دیفرانسیل، پلیمورفیسم،
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
چکیده انگلیسی
There has been a long controversy regarding the glass transition in low-density amorphous ice (LDA). The central question is whether or not it transforms to an ultraviscous liquid state above 136Â K at ambient pressure prior to crystallization. Currently, the most widespread interpretation of the experimental findings is in terms of a transformation to a superstrong liquid above 136Â K. In the last decade some work has also been devoted to the study of the glass transition in high-density amorphous ice (HDA) which is in the focus of the present review. At ambient pressure HDA is metastable against both ice I and LDA, whereas at >Â 0.2Â GPa HDA is no longer metastable against LDA, but merely against high-pressure forms of crystalline ice. The first experimental observation interpreted as the glass transition of HDA was made using in situ methods by Mishima, who reported a glass transition temperature Tg of 160Â K at 0.40Â GPa. Soon thereafter Andersson and Inaba reported a much lower glass transition temperature of 122Â K at 1.0Â GPa. Based on the pressure dependence of HDA's Tg measured in Innsbruck, we suggest that they were in fact probing the distinct glass transition of very high-density amorphous ice (VHDA). Very recently the glass transition in HDA was also observed at ambient pressure at 116Â K. That is, LDA and HDA show two distinct glass transitions, clearly separated by about 20Â K at ambient pressure. In summary, this suggests that three glass transition lines can be defined in the p-T plane for LDA, HDA, and VHDA.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Non-Crystalline Solids - Volume 407, 1 January 2015, Pages 423-430
Journal: Journal of Non-Crystalline Solids - Volume 407, 1 January 2015, Pages 423-430
نویسندگان
Thomas Loerting, Violeta Fuentes-Landete, Philip H. Handle, Markus Seidl, Katrin Amann-Winkel, Catalin Gainaru, Roland Böhmer,
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