کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7902987 | 1510455 | 2014 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
71Ga NMR in chalcogenide and chalco-halide glasses
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: 71Ga NMR in chalcogenide and chalco-halide glasses 71Ga NMR in chalcogenide and chalco-halide glasses](/preview/png/7902987.png)
چکیده انگلیسی
Chalcogenide and chalco-halide glasses containing gallium have been studied through 71Ga solid state nuclear magnetic resonance (NMR). An unusual line shape of the 71Ga NMR spectra has been observed for the first time. This line shape was ascribed to the preferential local symmetry existing around gallium atoms in these glasses which are characterized by the covalent character of their chemical bonds. Then, the local environment of gallium in Ga2S3-GeS2-CsCl glasses was studied by 71Ga NMR as a function of the ionic cesium chloride CsCl concentration. In this system, CsCl directly interacts with Ga by forming anionic complexes, modifying its environment. The Czjzek's electric field gradient distribution and its recent extension have been successfully applied to reconstruct the experimental 71Ga NMR spectra. These results highlight the evolution of local surroundings of Ga atoms in the glass network as a function of the CsCl concentration.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Non-Crystalline Solids - Volume 383, 1 January 2014, Pages 216-221
Journal: Journal of Non-Crystalline Solids - Volume 383, 1 January 2014, Pages 216-221
نویسندگان
Yannick Ledemi, Bruno Bureau, Gérard Le Caër, Laurent Calvez, Claire Roiland, Grégory Tricot, Pierre Florian, Virginie Nazabal, Dominique Massiot,