کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7921169 1511746 2018 13 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Graphene nanosheets obtained through graphite powder exfoliation in pulsed underwater electrical discharge
ترجمه فارسی عنوان
نانو ذرات گرافن به وسیله اکسفالیزاسیون پودر گرافیت در تخلیه الکتریکی پالس زیر آب به دست آمده است
کلمات کلیدی
تخلیه الکتریکی آب زیرزمینی، گرافن، لایه برداری، حلالها،
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد مواد الکترونیکی، نوری و مغناطیسی
چکیده انگلیسی
Graphene nanosheets were produced by graphite exfoliation through underwater electrical discharge, also known as plasma underwater. Graphite particles were dispersed in different solvents with different ratios between polar and dispersive surface tension components (pure water and an aqueous solution of isopropyl alcohol (IPA) at different concentrations (1:1 and 7:3 IPA:Water)) under constant stirring and low voltage pulses (about 1.5 kV). Even under relative low voltage, the production of graphene was observed in all solvents with the most of the graphene sheets containing less than 10 monolayers. Results show that further affinity between the surface tensions of the graphite and the solvents influenced in the characteristic of the graphene obtained. The 7:3 IPA/water solution has a similar ratio between polar and dispersive surface tension components to the graphite and the mixture. Exfoliation product obtained with this mixture presented an intense peak at ∼284.3 eV, which is corresponding to sp2 binding, characteristic of the graphene. However, in this solution, it was observed further break of C-C bonds and a significant reduction of its surface area. Smaller graphene flakes sizes present more C-O contents due to the carboxyl groups be more likely to form at graphene edges than at defect sites within the basal plane.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Chemistry and Physics - Volume 217, 15 September 2018, Pages 1-4
نویسندگان
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