کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
8012821 1517163 2018 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Cu3SnS4@TiO2 anatase/rutile mixed-crystal nanorods p-n heterostructures: Controlled fabrication and efficient photocatalytic application
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فناوری نانو (نانو تکنولوژی)
پیش نمایش صفحه اول مقاله
Cu3SnS4@TiO2 anatase/rutile mixed-crystal nanorods p-n heterostructures: Controlled fabrication and efficient photocatalytic application
چکیده انگلیسی
A novel high efficient p-n heterostructure photocatalyst is well designed and firstly realized on coupling electrospun TiO2 anatase/rutile mixed-crystal nanorods (T-A/R-NRs) and p-type ternary Cu3SnS4 (CTS), which is a hot photosensitive material in photovoltaics but rarely attracted in photocatalysis. Such configured CTS@T-A/R-NRs shows 2.02 eV band-gap and are demonstrated to be more efficient in photocatalytic degradation. The optimized CTS@T-A/R-NRs with 24 h hydrothermal reaction possesses a superior degradation rate of 1.3980 h−1, which is 2.5 and 4.3 times than T-A/R-NRs (0.5490 h−1) and CTS (0.3240 h−1). It is mainly attributed to the better morphology for high light-harvesting, the established built-in electric field at p-n interfaces and special anatase/rutile mixed-crystal structure of TiO2 for efficient separation of photogenerated charges. The study indicates a promising strategy in designing potential nanostructures to simultaneously achieve high efficient photocatalytic degradation and photovoltaic conversion.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Letters - Volume 225, 15 August 2018, Pages 37-41
نویسندگان
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