کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
8012834 1517163 2018 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Directly deposited porous two-dimensional MoS2 films as electrocatalysts for hydrogen evolution reactions
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فناوری نانو (نانو تکنولوژی)
پیش نمایش صفحه اول مقاله
Directly deposited porous two-dimensional MoS2 films as electrocatalysts for hydrogen evolution reactions
چکیده انگلیسی
Two-dimensional (2D) MoS2 has recently emerged as an efficient hydrogen evolution reaction (HER) catalyst due to its unique atomic layered structure and stability in harsh acidic environment. However, the high electrochemical performance of MoS2 is still limited to edges of its 2D layers. Here, we report the synthesis of highly porous MoS2 films exhibiting a large density of edge sites by using a direct sputter deposition method. Interestingly, the as-deposited MoS2 films resulted into a 3R phase with nano porous structure which is attributed to the lattice relaxation and high energy of sputtered ions. The as-synthesized porous MoS2 nanostructures demonstrate an excellent electrocatalytic performance with a low HER onset potential of ∼0.2 V, long-term cycling stability, and a low Tafel slope in the range of ∼80-90 mV/decade at a high cathodic current density.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Letters - Volume 225, 15 August 2018, Pages 65-68
نویسندگان
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