کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
8017170 | 1517215 | 2016 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Spherical Li1.95Na0.05FeSiO4/C composite as nanoporous cathode material exhibiting high rate capability
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فناوری نانو (نانو تکنولوژی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Nanoporous spherical Li1.95Na0.05FeSiO4/C and Li2FeSiO4/C composites have been synthesized through a spray drying-assisted method. The effect of Na doping on the physicochemical properties of Li2FeSiO4 is extensively investigated by X-ray diffraction, scanning electron microscopy, transmission electron microscope, AC impedance spectroscopy, four-point measurement and galvanostatic charge-discharge testing. It is found that Li1.95Na0.05FeSiO4/C composite exhibits superior rate capability and cycling stability. Remarkably, even rate increases to 10C, a high discharge capacity of 110 mAh gâ1 is obtained, and 97.8% of its initial value is retained after 100 cycles at 2C. The excellent electrochemical properties were mainly attributed to enhancement of electronic conductivity and reduction of charge transfer resistance.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Letters - Volume 173, 15 June 2016, Pages 207-210
Journal: Materials Letters - Volume 173, 15 June 2016, Pages 207-210
نویسندگان
Yurong Ren, Peng Lu, Xiaobing Huang, Jianning Ding, Haiyan Wang, Shibiao Zhou, Yuandao Chen, Xiang Ding,